Abstract
Thallium cyclopentadiene (Cp) salts are important precursors for the synthesis of a variety of compounds having materials and commercial applications. The synthesis of 5,6-fused ring thallium Cp pyridazines 2a–d from previously reported 5,6-fused ring pyridazines is described herein. This route was quite general, and features an efficient and convenient two-step synthesis of a series of TlCp salts in a THF solution of thallium ethoxide. Full characterization of newly formed TlCp salts 3a–d are reported.
Jason O. E. Young, Chad A. Snyder, Nathan C. Tice, Seth L. Sloan, Adam C. Smith, Sana A. Shah, Levi A. Dopierala, Michael S. Crocker, Yuto Kobayashi & Michael G. Mazzotta (2013) Synthesis and Characterization of Some Thallium Cyclopentadienide Fused Ring Pyridazines,Synthetic Communications, 43:18, 2441-2451
https://doi.org/10.1080/00397911.2012.698356